- Open Access
A new technological approach to the granulation of slag melts of ferrous metallurgy: obtaining glassy fine-grained granules of improved quality
Journal of Engineering and Applied Science volume 68, Article number: 22 (2021)
The technological factors required to improve the operational properties of granulated metallurgical slags demanded in the building industry have been analyzed. In order to satisfy these factors, a new technology for hydro-vacuum granulation of slag melts (HVG) has been developed. It is shown that the main advantage of the proposed HVG process is the provision of forced high-speed vortex convection of water, with the effect of vertical suction, crushing, and degassing of the three-phase (water–slag granules–water vapor) heterogeneous medium formed during the overcooling and solidification of slag. It is proved that the high-speed volumetric disintegration and overcooling with the degassing effect sharply reduces a degree of aggressive gas/vapor impact on the being cooled particles of slag, which, in turn, leads to the reduction of the perforation degree of the granules. The obtained granules are distinguished by stable fractionation and improved, well-defined dense amorphous glassy structure, the water-holding capacity of which has reduced from 45–50% to 25–13%, the actual moisture content from 24–20% to 6–4%, while the hydraulic activity in terms of CaO-uptake increased from the conventional 320–360 mg/g to 610–650 mg/g. Pilot scale research demonstrated that the designed equipment for the HVG technology allows sustainable control of the quality of granules, and it has the potential for further development and implementation.
In connection with inevitable depletion of metal-bearing mineral resources, increased expenses on mining and beneficiation, and the continuous growth of mitigation costs for rehabilitation and reclamation of disturbed lands, the modern mining and metallurgical complexes will be increasingly forced to adapt to such new realities of their functioning as a necessity for strict minimization of production losses and intensification of treatment processes of accumulating industrial waste with the aim of their highest possible valorization [1,2,3,4].
Among the wastes of the metallurgical production of ore-reduction profile (blast furnace and electrocarbothermic production of pig iron and ferroalloys), slag melts generated as by-products during metal/alloy smelting rank first by their scale and ecological hazard. In many cases, the amount of slag generated significantly exceeds the volume of metal produced. Material costs for their evacuation and preparation for subsequent processing increases the cost price of basic products, which reduces profitability and worsens the overall competitiveness of the industrial enterprise. A partial compensation of the above problems is possible by the local, in-plant mastering of the heat and power resource potential of these slag melts. The most efficient way of mastering the thermophysical energy of slags is its utilization for heating water and vapor generation  or, in some cases, for sintering (agglomeration) of fine-grained metallic charge . In its turn, the use of these slag melts in the granulated form in the manufacture of building, ceramic, and sorption materials is another rational way for mastering their more valuable mineral-resource potential [7,8,9,10,11,12,13]. During granulation, due to rapid cooling (quenching), the slag solidifies in a glassy (amorphous) state and the latent heat of crystallization (300–400 kJ/kg) is not released and is realized in the form of chemical energy, giving the slag a valuable quality – hydraulic activity. Valorization of slag melts of metallurgical production by way of granulation will, in addition to extra financial gain, lead to an essential reduction of exploitation and ecological costs on long-term storage of these slags .
Among numerous methods of granulation of slag melts, the most progressive and cost-effective are considered the technologies wet granulation from VNIIMT (Scientific-Research Institute of Metallurgical Heat Engineering, Russia) and Paul Wurth technologies - INBA process (SMS Group, Luxemburg) [15, 16]. According to research [17, 18], these technologies are economical by 15–30 % in comparison with such methods as the channel-pool, hydro-channel, or drum granulation. In the first turn, this is conditioned by a reduction of the fleet of slag cars and the number of the operative personnel, as well as the efficiency of processing of molten slags (loses on ladle sculls are reduced). A particular feature of the VNIIMT and Paul Wurth technology is also their environmental friendliness, minimized emission of particularly noxious gases H2S и SO2 and reduced consumption of the used process water. The main disadvantage of wet granulation technologies is a high degree of structural and granulometric heterogeneity of the obtained granules, as well as a high degree of swelling and perforation, which as a result leads to a significant reduction in their quality.
Lately, some country has started to investigate and develop experimental technologies of dry granulation of molten slags with the use of centrifugal units, by analogy with the technology of powder formation from iron melts [19,20,21]. The system of dry, drum-ball granulation of slag with the possibility of heat recovery is also being piloted . However, based on a critical analysis of the published research, it can be noted that the major shortcoming of these technologies will be reduced productivity, high intensity of failures, and high price of repair. The main advantage of the method of dry granulation of liquid slag melts is a possibility of producing granules with a denser and stronger structure. But, due to a reduction in speed and depth of slag melt overcooling (quenching), a content of particular importance for manufacture of building materials, amorphous, hydraulically active glassy phase (HAGP), is reduced in the obtained granulate. This essentially reduces the granulate quality, since it leads to a necessity of its artificial activation .
According to the European standard BS EN 15167-1: 2006 and studies [24, 25], the main criteria of granulated slag quality evaluation are the actual content of glassy amorphous phase, which must be at least 66.6% and a specific surface area 3750–4500 cm2/g, obtainable after milling. To achieve this indicator, the granulated slag is subjected to mechanical milling, predominantly up to a fraction of 0–75 μm. Studies [16, 17] also note the need to control such important indicators as the initial water-holding capacity (WHC) of non-milled (primary) granulate and the actual moisture content (AMC). AMC of the ready-for-shipment granulate, depending on its production technology, can change within 8–24%. Accordingly, the consumption of water during granulation, including the losses on steam emission may constitute rather impressive figures from 1 to 3.5 m3/t. Moreover, the pellicular moisture and the water retained in the pores of granules represent the unnecessary dead weight at transportation. The need of its evaporation during the production of building and ceramic materials leads to an essential overspend of fuel materials used for the purpose. In addition, the freezing of the transported wet granulated material in wintertime is quite frequent, also leading to great problems in servicing railroad freight cars.
Modern technological approaches mainly aimed at the handling of the problem of quality improvement of the slag granulate by reducing the WHC and AMC directed at controlling the size and shape of the obtained grains towards an essential lowering of the specific share of fine fraction <1÷1.25 mm [17, 18, 26]. However, with the growth in size of granules, the temperature conditions of cooling worsened, and the HAGP formation is less intensive. Deterioration of the activity of slag granulate leads to the need for additional chemical, mechanical, or thermal activation, which worsens the technical and economic indicators of its application [27,28,29].
From the point of view of the maximum useful use of the resource potential of treatment slag melts, the issue of extraction of metal and graphite inclusions present in it also deserves special attention. According to the study , the content of metal scrap and free (flake) graphite in metallurgical slags can vary within 4–6 and 4.5–15%, respectively. The method of metal and graphite inclusions extraction proposed here, provides mechanical or explosive grinding of solid slag to 0–10 mm in dimension, followed by gravity-magnetic and aeration separation of the formed fine slag-metal-graphite mechanical mixture. The process is very time-consuming, costly, and environmentally unsafe (dusty). In addition, known is a method of extracting free graphite from slag by acid leaching of products of its mechanical separation (graphite is precipitated in the cake) [31, 32].
In case of substantial, purposeful modernization, the technology of wet granulation of slag melts can successfully combine the function of separation machining. But, the most important thing to note is that only wet granulation is able to continuously, with high productivity, produce 99% amorphous granulate [33, 34], because of which it will always have an advantage over dry granulation methods. According to a study , the main condition for achieving such a high degree of amorphization is the need to keep the slag superheat at 160 K, above the glass transition temperature Tg (Tg≥Tliq), with a cooling (quenching) rate of 2.6×105 K s−1. However, the problem of managing such important indicators of the quality of primary (not milled) granulate, as HWC and AMC, neither in these nor in other studies, is not investigated. The problem of self-abrasion (self-grinding and dusting) is also poorly studied, which during transportation, stockpiling and application of these raw materials leads to both undesirable losses and dust pollution of the surrounding air basin. Since WHC and AMC depend on the degree of surface roughness and external (open) porosity of granules, and the resistance to self-abrasion—on the structural and mechanical strength, the control of these characteristics becomes a very topical task.
Based on the above analysis, the purpose of this study and its novelty is to create and investigate a new, improved technology and equipment of high-speed wet granulation of slag melts, providing the maximum yield of hyper-quenched, mechanically strong and dense, abrasion-resistant amorphous glassy granules with reduced surface roughness, with minimal WHC and AMC, purified from metal and graphite inclusions.
The solution of this problem requires an updated approach to wet granulation technology, the essence of which should be to ensure high-speed fine fractional <1 mm dispersion of molten slag with the maximum possible degree of overcooling (amorphization) and complete exclusion of the effect of steam-gas swelling and perforation.
Creation of such conditions is possible in case of using a special, closed, sharply expanding granulation chamber, with the function of forced internal high-speed vortex convection of water flowing around the dispersable slag stream (jet), thus creating an axial (vertically directed) continuous wave of hydraulic rarefaction (vacuum).
Materials and methods
In the experimental studies, we used production slags from the Rustavi Metallurgical Plant (Georgia), which were melted in a laboratory single-phase electric arc furnace with an active power of 100 kVA. The oxide melts obtained for the experimental studies corresponded by their chemical composition to the slags from the production of gray and foundry pig iron (GPIS and FPIS) and to the low-carbon constructional electrical steel (LCCESS). The experimental research took place in the foundry of the Georgian State Scientific Technical Center “Delta.”
The chemical composition and such particularly significant technological characteristics as the basicity modulus (BM) [BM= (СаО+MgO)/(SiO2+Al2O3)], the activity modulus (АM) [АM=Al2O3/SiO2], the initial granulation temperature—Т, K, and viscosity—μ, Pa·s are presented in Table 1. The content of metallic inclusions (beads with a diameter of 3 mm or less) in GPIS is 4.3%, in FPIS—5.2%, and in LCCESS—7.5% and the content of flake graphite—4.5, 6, and 8.4%, respectively. Characteristics of technical water used for wet granulation are as follows: initial temperature—293 K; weakly acid-neutral medium—pH 6.5–7.5; average mineralization, dry residue—200–400 mg/dm3; average hardness—3–5 mg-eq/dm3; high transparency, suspended solids content—4.5 mg/dm3.
For experimental investigation, we used our developed pilot semi-industrial hydro-vacuum unit for dispersion of metallurgical melts . Based on the results of our previous studies [36,37,38], we can state that the advantages of this innovative approach lie in the complex hydrodynamic-cavitation-vacuum thermomechanical treatment of vertically sucked and dispersible melt. The conditions for disintegration and cooling of the granulated slag melt created here are radically different from all of the above-discussed treatment methods.
The metallurgical melts hydro-vacuum dispersion process, when adapted to specific conditions of granulation of slag melts in the iron, steel, and ferroalloy production in blast and electric arc furnace, schematically illustrated in the Fig.1. At the same time, the developed new technological system for the processing of slag melts additionally solved such acute problems as separation/extraction of particularly valuable metallic inclusions and settling of the flake graphite washed-out from the slag.
The experimental semi-industrial plant of hydro-vacuum granulation of slag melts, which was tested at the State Scientific and Technical Center “Delta,” is illustrated in Fig. 2.
Main operating conditions of a hydro-vacuum plant are as follows: supplied water pressure—15÷16 bar, water supply feed—150÷200 m3/h, suction capacity—0.8÷0.9 bar, diameter of the operating channel of the replaceable melt-supplying tip—15÷30 mm, diameter of the outer cylindrical body of the plant—150 mm, inside diameter of the diffusor-dispenser—100 mm, plant height—2 m, occupied area—15, and performance—150÷300 kg/min.
Disintegration of vertically pumped slag melt, separation of metallic and graphite inclusions, and subsequent fine crushing of slag droplets are carried out by means of tangential and angular water-jet blows of the toroidal water blast generated in the diffusor (2) of the vertically located hydro-vacuum plant (1). This dribble is also subjected to the force impact from numerous high-power and high-frequency shock waves (4), originating at the formation of the alternating pulsed field (front) of the tangential (axial) pressure. The so generated cavitation processes continue to fine the setting particles of the disintegrated melt. Totality of the processes of cavitation ultrasound shock treatment, due to the raised potential оf inertial acceleration releases the remaining in the slag dribble the finest metallic beads. At that, the high-speed quenching and volumetric contraction of the settling particles lead to the formation of new cracks, resulting in the release of the sour gas localized in the slag particles. The dynamic, high-speed solution and removal of gases and steam formed in the granulation process from the centers of their emission lead to a decrease in the structure swelling and perforation.
Based on the above features of the HVG process, its main advantage could be named the ensuring of forced high-speed cellular convection of the water supplied to the dispersion unit, where, in contrast to conventional granulation technologies, the disintegration process is restricted by the formation of local microsecond pulse zones of the undeveloped bubble boiling, at which the generated vapor-gas formations fail to impact aggressively the forming structure of solidifying slag melt particles and do not contribute to its swelling and perforation. Consequently, slag grains produced by hydro-vacuum granulation will be distinguished by their structural homogeneity, density, thin-walled (flake shape), and a high gradient of quenching.
For morphological analysis of the surfaces of the obtained granules, the method of scanning electron microscopy (SEM) was used; the method of energy-dispersive X-ray analysis (EDS) was used to determine the elemental composition of these samples, and the method of X-ray diffraction analysis (XRD) was used to determine the phase composition. Methods of differential thermal and thermogravimetric analysis were used to study chemical and physicochemical processes occurring in a substance under conditions of temperature regime change (phase transformations).
The indicator of the development (roughness) of the granule surface, important in terms of its water-holding capacity, was determined by the method of optical profilometry. A liquid (kerosene) pycnometer method was used to evaluate porosity. To assess the abrasion resistance, a TUMBLER 1000 R tester (EN 15210-1) was used. For a quantitative assessment of hydraulic activity of the obtained granules, the lime absorption method (СаО) was used . For this purpose, hydrate of lime (Са(ОН)2) with the density of 1.0 g/cm3 was prepared. The СаО concentration change was controlled with a 24-h periodicity by a titrimetric method and 1 Н solution of hydrochloric acid, according to GOST 22688-2018 . The experimental data were processed by the method of analysis of variance.
The morphology and EDS and XRD spectrograms of granules obtained by hydro-vacuum granulation of the most demanded slag melt GPIS presented in Fig. 3, where image (а) shows that the grain surface is smooth and glassy, without crystalline-ribbed roughness, grains do not contain open (through) pores and metallic inclusions. Relatively small granules consist smoother and more transparent glass formations. For a comparative analysis of surface morphology, Fig. 4 shows SEM images of the granules obtained by traditional and proposed wet granulation methods. The average height of the protrusions on the surface of conventional granules, as determined by optical profilometry, is on average 35 μm and the average depth of the grooves is 45 μm. The average height of the protrusions on HVG granules is only 5 μm, and the depth of the grooves is practically non-existent, which gives the latter a significant advantage in terms of moisture holding capacity.
The result of X-ray phase spectral analysis of granulated GPIS melt Fig. 3(b) (grain size 0.5–1 mm) shows that the obtained diffractogram does not reveal clearly distinguished diffraction peaks of the crystal component, the structure mainly consists of a glassy, hydraulically active amorphous phase, but the background presence of inclusions of mineral formations close in composition to gehlenite Ca2Al2SiO7, merwinite Ca3Mg(SiO4)2, shennonite (γ-2CaO∙SiO2), larnite (β-2CaO∙SiO2), goethite (α-FeO∙OH), and hematite (α-Fe2O3) is still identified. The number of inclusions of the noted mineral formation (MF) is reduced when the grain size of granulate (D, mm) decreases by dependence MF=0.8D+0.36, which is possible by increasing the degree of hydro-vacuum crushing and quenching by increasing the pressure of water supplied to the hydro-vacuum disperser (Fig. 1, positions 2 and 3). It is noteworthy that the slags granulated by traditional methods also contain crystalline inclusions of acermanite (Ca2Mg(Si2O7)), manganolite (Ca3Mg(SiO4)2), melilite (Ca2(Mg0.5Al0.5)·(Si1.5Al0.5O7)) and merwinite (Ca3Mg(SiO4)2), which makes them noticeably inferior in hydraulic activity to HVG granulate. In contrast to the conventional granulation technologies, in which the glassy phase content (HAGP) in the obtained granules is unstable and varies depending on their grain size, degree of loosening, swelling and volume overcooling (quenching), the HVG process can stably produce granules homogeneous in key characteristics and properties, which once again emphasizes its high efficiency.
The high degree of glazing of HVG granules is also evidenced by the results of differential thermal analysis, which are illustrated in Fig. 5. The derivatogram of HVG granules shows that at 1170 K an exothermic effect (release of latent heat) corresponding to the glass crystallization (reverse phase transformation from amorphous to crystalline state) is observed. It is preceded by endothermic effect (without mass loss) at 1130 K related to energy expenditures on bond rearrangements in the glassy phase before its crystallization. The endothermic effect at 1090 K may be caused by the polymorphic transformation of shennonite (γ→α). The broad endothermic effect at 1225 K corresponds to the beginning of glassy amorphous phase decomposition. For hematite (α-Fe2O3), a small endothermic effect at 990 K caused by its transition into γ-Fe2O3 maghemite is characteristic, accompanied by an abrupt change in properties.
Crystalline iron oxide monohydrates have three modifications: α (goethite), β, and γ (lepidocrocite). The differential curve of goethite (α-FeO∙OH) has an endothermic effect in the temperature range from 600 to 690 K caused by its dehydration with transition to anhydrous crystal form α-Fe2O3 (hematite). On the DTA curve, the endothermic effect also appears at 990 K, which is associated with the polymorphic transformation of α-Fe2O3 into γ-Fe2O3. A broad endothermic effect at 410 K is associated with removal of adsorbed moisture on the surface of the slag particle. Small endothermic effects at 470, 550, and 600 K are caused by the removal of hygroscopic moisture in β-modified iron oxide monohydrate (β-FeO∙OH), the content of which does not exceed 0.5 wt.%. Analysis of phase transformations with accompanying mass losses shows that the content of the crystalline phase in the granules does not exceed 1.5–1.6%. Thus, we can conclude that the GPIS granulate obtained by hydro-vacuum granulation on average by 98.5% consists of glassy, solidified in the amorphous state grains with micro inclusions of crystalline dicalcium silicate (shennonite, larnite), iron oxides (hematite, maghemite), and their hydrates (goethite, lepidocrocite). The phase composition of HVG granulate produced from FPIS melt practically did not differ from GPIS granulate. The only difference is the decrease in the ratio between of mineral compounds of Ca2Al2SiO7 to Ca3Mg(SiO4)2 by 18–20 % (graphically unrepresented). In turn, the phase composition of the LCCESS granulated by the hydro-vacuum method was slightly different from composition of GPIS. In particular, the samples were 95–96% composed of the glassy phase, with inclusions of merwinite (Ca3Mg(SiO4)2), magnesioferrite (MgFe2O4), larnite (Ca2SiO4), wustite (FeO), and goethite (FeO∙OH). In spite of the fact that HVG granulate LCCESS also consisted to a high degree of the glassy phase, its hydraulic activity was still significantly lower (by 25–20%) than that of HVG slag GPIS and FPIS, which can be explained by its relatively low AM (Table 1).
The results of the study of hydraulic activity of the most highly demanded GPIS granulate are given in Fig. 6, where the impact of granule size (D, mm) and the length of reaction with the lime (in days) per value of its absorption in milligram per gram is illustrated. The comparative deceleration of the lime absorption rate observed in granules of higher grain size can be explained by both a decrease in the specific area of the reacted surfaces and a possible rise in the presence of above noted microcrystalline mineral formations (MF=0.8D+0.36).
Figure 6 shows that the average СаО-absorption activity of granules produced in the HVG process makes 600–650 mg/g, which is almost two times higher than that of slag granulated by traditional technologies (320–360 mg/g ). This testifies to the obvious advantage of the technological conditions of high-speed degassing, globular-thin-walled (flake) dispersion, and high-gradient quenching, created during hydro-vacuum granulation of the slag melt.
Since the granulate activity depends to a considerable extent on its grain particle size (D, mm), an investigation for detecting the factors of its control was carried out. The main factors of technological were found to be the temperature (T, K) and the internal diameter of the melt feeding nozzle, i.e., the flow fed in the diffusor (d, mm).
The main results of this research are given in Fig. 7. From Fig. 7 (1), it can be seen that at hydro-vacuum granulation of the close in chemical composition GPIS and FPIS melts, at the 15 mm diameter of the feeding flow, the treatment temperature decrease from 1720 to 1600 K which leads to the coarsening of the produced at the output granules from 0.2 to 1.9–2 mm. At treatment, flow d=20 mm, and the average diameter of the granules grows from 0.26–0.3 mm to 2.4–2.5 mm. An increase in the flow diameter up to 25 mm gives an increase in the size of granules from 0.33–0.35 to 2.9–3 mm; during dispersion of the 30-mm flow, the granules coarsen from 0.4 mm to 3.5–3.7 mm. In turn, Fig 7 (2) shows that during treatment of the relatively viscous LCCESS melt, a reduction of its initial temperature from 1830 tо 1690 K, at dispersion of the 15 mm diameter flow, is accompanied with the coarsening of the average size of granules from 0.25 tо 2.2 mm. An increase in the diameter up to 30 mm and accordingly as relative doubling of the melt supply rate at the given temperature range led to the coarsening of the granules from 0.4 to 4.3 mm.
Figure 7 graphical dependences indicate on the existence of a stable essential correlation between the controlled parameter (grain size) and regulated technological melt treatment modes, which, in turn, can become an functional lever to operating control of the HVG process efficiency by choosing the rational values of these modes.
Analysis of the laboratory data showed that the fine, thin-walled semi-transparent particles of average size of 0.5–0.4 mm and lower are distinguished by the highest activity. Based on the above, the temperature meeting the condition D ≤ 0.5 mm could be taken as the temperature threshold of high efficiency of the HVG process. Based on the noted threshold criterion and data with given in Fig. 7 (1), the rational temperature for the GPIS and FPIS melts can be considered 1680 K. In its turn, the recommended temperature for the LCCESS melt is 1790 K.
Laboratory studies on the porosity and abrasion resistance of granules obtained by the HVG method, similarly to studies on hydraulic activity, showed a clear advantage of the HVG process over traditional granulation methods. On average, the porosity of HVG granules, depending on their fractionality (0–4 mm), was in the range of 5–20%, which is actually 2.5–3 times lower than the porosity of granules produced by traditional wet methods. In turn, the loss of mass during self-abrasion was 3–5%, which is 3.5–4 times lower than the index of abrasibility of granulated slag produced by traditional technologies.
The application of the similar method for assessing the HVG process efficiency by the operational characteristics of WHC and AMC showed that in contrast to the conventional hydromechanical INBA or VNIIMT technologies, where the WHC of the obtained from GPIS и FPIS granulate, depending on the grain particle size, can vary within 45–50%, the AMC 24–20%, during hydro-vacuum granulation, the WHC reduced to 25–13%, and the AMC to 4–6%. The noted quality indicators also significantly improve in the LCCESS granulate. Dependence of the WHC and AMC of granulate obtained by the HVG technique on its grain size is illustrated in Fig. 8.
The effect of perforation reduction degree and improvement of the WHC indicator is also clearly depicted in SEM images (Fig. 9), illustrating the surfaces of GPIS melt granules produced by the conventional hydro-channel (Fig. 9(1)) and the proposed hydro-vacuum technology under different temperature conditions of treatment (Fig. 9 (2–4)). The SEM images of surfaces of the granules produced by the HVG technique indicate on both an essential reduction of the chadded perforation and a reduction of the scale of volumetric swelling. At that, with a decrease in the granulation temperature from 1720 to 1680 K, i.e., with a limiting increase in viscosity and surface tension of the processable melted slag, the structure and morphology of the granules are improved and stabilized. This effect is another proof of essential advantage and necessity of selecting an optimum temperature range of processing the melted slags in the process of their hydro-vacuum granulation. So, unlike new HVG process, in conventional technological processes of wet granulation, at technological losses of heat, decrease in temperature, and fluidity of processed slag melt, structure and morphology of granules with an increase in their grain size do not improve; on the contrary, their degree of swelling increases, degree of quenching decreases, and as a result, content of hydraulically active glassy amorphous phase can fall below the limiting value of 66.6%, fixed by the European standard BS EN 15167-1: 2006. The self-abrasion rate also deteriorates, reaching 30% or more.
The HVG process also showed its high efficiency in terms of separation and extraction of metallic spherical particles and flake graphite included in the slag. Figure 10 shows the effect of separation of metal inclusions from slag melt (fractionality 50–200 μm). The degree of extraction depending on the temperature and viscosity of the slag varies in the range of 90–95%, a slightly lower index of graphite extraction—75–80%. Studies on determination of rational approach and regimes of separation of granulated slag and metal and graphite inclusions present in it are still in progress.
A system analysis of advantages and features of the semi-industrial pilot HVG-plant showed that its operation for granulation of slag melts of ferrous metallurgy in enterprises equipped with modern arc electro-thermic ore-smelting furnaces is feasible according to the schematic diagram presented in Fig. 11, where 1 is arc ore-thermal furnace, 2—chute for intake and primary processing (liquid-phase separation) of slag-metal melt mixture , 3—conveyer for casting liquid metal (LM) cleaned from associated slag, 4—container for receipt of solidified metal pigs (MP), 5—plant for hydro-vacuum suction and granulation of molten slag, 6—high-pressure water pump, 7—technological unit of continuous pulp (P) processing: separation and precipitation of metal inclusions, dehydration of slag granulate (SG), extraction of graphite (G), and return water supply, 8—granulated slag intake and final dehydration tanks, and 9—collector of extracted metallic beads (MB).
The pilot scale research of the proposed technological approach and plant for hydro-vacuum granulation of metallurgical slag melts showed that its scaling under the real industrial conditions will not be associated with outages and essential reconstruction of melting furnaces or the adjacent casting platform.
It was also revealed that in the case of significant overheating of the slag and the impossibility of regulating the temperature during hydro-vacuum treatment, the need to a proportional increase the pressure of the high-speed water flow used for granulation becomes paramount. A magnification in the feed rate and water pressure, together with an increase in the rate of suction (vacuuming capacity) and granulation of liquid slag, intensifies the heat removal process (accelerates the process of cooling and quenching the forming granules), which sufficiently compensates the deviation from the desired temperature regimes of processing. Due to the need to increase the water pressure, the power consumption increases only slightly, but with an increase in the productivity of the HVG-plant, this consumption is also fully compensated. Accordingly, the quality, safety, and economic performance of the HVG process do not deteriorate.
Based on the studies conducted, we can conclude that the proposed technological approach to granulation of slag melts is highly effective and has a number of significant advantages, in particular it is:
Ensuring high-speed fine-fractional (flake) dispersion, degassing, and high-gradient quenching of slag melt with the elimination of swelling and vapor-gas perforation of hardening particles;
Ensuring a high degree of quenching and amorphization, the content of the glassy phase 95-99%, depending on the chemical composition and modulus of basicity and activity of the slag melt;
High reliability and safety of functioning at the expense of high-speed inhibition of the vapor formation and boiling processes, practically complete exclusion emission of dust, vapor and noxious gases;
Flexible control of the granulation process due to smooth regulating of technological modes (granulated slag temperature, suction jet diameter, suction power, water pressure);
Producing a granule with reduced water-holding capacity (WHC) and actual moisture content (AMC);
Possibility of separation and individual extraction of metal and graphite inclusions.
The rational temperature range of the hydro-vacuum granulation of molten slags of the gray and foundry pig iron is 1680-1660 K, during granulation of melted slags of low-carbon constructional steels the optimal is the temperature range 1790–1750 K.
On average, the porosity of HVG granules depending on their fractionality (4–0 mm) is reduced up to 5%, which leads to densification and refinement of the structure and reduction of self-abrasion index up to 3%. According to these characteristics, the quality of HVG slag is several times better than products made by traditional technologies. The water-holding capacity and actual moisture content of HVG granules can be reduced by up to 25–13% and 6–4%, respectively, and the hydraulic activity by CaO absorption index is increased up to 610–650 mg/g.
Based on the above results, in general, it can be concluded that the problem of developing an improved technology and equipment for wet granulation of slag melts providing the maximum yield of highly quenched, mechanically strong and dense, abrasion-resistant amorphous glassy hydraulic highly active granules with minimum water-holding capacity and moisture content has been successfully solved at the level of semi-industrial scale. Consequently, the proposed technological approach to granulation of slag melts has a prospect for further development and industrial implementation.
Availability of data and materials
The datasets used and/or analyzed during the current study are available from the corresponding author on reasonable request.
Slag activity modulus
Actual moisture content
Slag basicity modulus
Energy-dispersive X-ray spectroscopy
Foundry pig iron slag
Hydraulically active glassy phase
Gray pig iron slag
Low-carbon construction electrical steel slag
Scanning electron microscopy
- T g :
Glass transition temperature
- T liq :
The liquidus temperature
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Sakhvadze, D., Jandieri, G., Jangveladze, G. et al. A new technological approach to the granulation of slag melts of ferrous metallurgy: obtaining glassy fine-grained granules of improved quality. J. Eng. Appl. Sci. 68, 22 (2021). https://doi.org/10.1186/s44147-021-00019-7
- Slag melt
- Hydro-vacuum granulation
- Extraction of metal and graphite inclusions