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Table 5 The comparison of values of Ea/(kJ mol−1) obtained from different methods as well as the relevant statistical quantities for reactions of MgO with carbonic reductants in different molar ratios and at temperatures 1723.15 K, 1748.15 K, 1773.15 K, 1798.15 K, and 1823.15 K

From: Systematic kinetic study of magnesium production using magnesium oxide and carbonic materials at different temperatures

 

MgO:Charcoal (1:1)

MgO:Charcoal (1:2)

MgO:Petcoke (1:1)

MgO:Petcoke (1:2)

Ea, 1723.15

481.2313

690.8303

Ea, 1748.15

481.0725

690.3459

Ea, 1773.15

480.9167

348.4596

689.8742

384.7295

Ea, 1798.15

480.7639

348.4596

689.4146

384.7295

Ea, 1823.15

480.6140

348.4596

688.9670

384.7295

SD

0.2440

4.0194 × 10−14

0.7366

6.9619 × 10−14

RSD

5.0744 × 10−2

1.1535 × 10−14

0.1068

1.8095 × 10−14

Range

0.6174

5.6843 × 10−14

1.8633

0

Mean

480.9197

348.4596

689.8864

384.7295

Ea, NL_Arra

487.1059

349.7380

501.1278

411.4653

Ea, L_Arrb

533.4443

281.0194

1000.5536

488.6408

Ea, Ref. [23]

468.4

419.1

  1. aNon-linear Arrhenius Fitting
  2. bLinear Arrhenius Fitting