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Table 4 The parameters obtained from fitting of final values of k by Eq. (8) and the relevant statistical quantities of fitting [30] for reactions of MgO with carbonic reductants in different molar ratios and at temperatures 1723.15 K, 1748.15 K, 1773.15 K, 1798.15 K, and 1823.15 K

From: Systematic kinetic study of magnesium production using magnesium oxide and carbonic materials at different temperatures

 

MgO:Charcoal (1:1)

MgO:Charcoal (1:2)

MgO:Petcoke (1:1)

MgO:Petcoke (1:2)

A/(K−B min−1)

881243424.7861

6745162.4300

908504046.5483

84223579.3924

B

0.2510

3.1695 × 10−13

1.6029

2.2265 × 10−14

C/KD

70055.7717

41910.0601

139511.1051

46272.3206

D

1.0307

1

1.0850

1

RSQ

0.9903

0.9548

0.9789

0.9631

RMSE

2.1819 × 10−5

Infinity

4.9679 × 10−5

Infinity

SSE

4.7609 × 10−10

1.7711 × 10−9

2.4680 × 10−9

4.6591 × 10−9

RSQNL_Arra

0.9902

0.9532

0.9311

0.9805

RMSENL_Arr

1.2662 × 10−5

4.2859 × 10−5

5.1820 × 10−5

4.9617 × 10−5

SSENL_Arr

4.8101 × 10−10

1.8369 × 10−9

8.0558 × 10−9

2.4618 × 10−9

RSQL_Arrb

0.9636

0.9947

0.9658

0.9997

RMSEL_Arr

0.1811

2.6988 × 10−2

0.3291

1.1373 × 10−2

SSEL_Arr

9.8376 × 10−2

7.2837 × 10−4

0.3249

1.2935 × 10−4

RSQRef [23].

0.9421

0.9895

RMSERef [23].

0.02

0.027

SSERef [23].

  1. aNon-linear Arrhenius Fitting
  2. bLinear Arrhenius Fitting